CATALYSE SUPRAMOLÉCULAIRE

 

Publications 2005-2008

1. Synthesis and Complexation Ability of a Novel Bis-(guanidinium)-tetrakis-(alpha-cyclodextrin) Dendrimeric Tetrapod as a Potential Gene Delivery (DNA and siRNA) System. Study of Cellular siRNA Transfection

   S. Menuel, S. Fontanay, I. Clarot, R.E. Duval, L. Diez, A. Marsura
   Bioconjugate Chem., 2008, 2357-2362 - doi: 10.1021/bc800193p

2. Easily accessible mono and polytopic β-cyclodextrin hosts by click chemistry

   M. Mourer, F. Hapiot, S. Tilloy, E. Monflier, S. Menuel
   Eur. J. Org. Chem. 2008, 5723–5730, DOI : 10.1002/ejoc.200800728

3. Carbon-supported ruthenium nanoparticles stabilized by methylated cyclodextrins : a new family of heterogeneous supramolecular nanocatalysts for gas phase hydrogenation of arenes.

   A. Denicourt-Nowicki, A. Roucoux, F. Wyrwalski, E. Monflier, A. Ponchel
   Chem. Eur. J. 14 (2008) 8090-8093.

4. Click chemistry as an efficient tool to access β-cyclodextrin dimers

   M. Mourer, F. Hapiot, E. Monflier, S. Menuel
   Tetrahedron 64 (2008) 7159-7163.

5. A property-matched water soluble homologue of the benchmark ligand PPh3.

   M. Ferreria, H. Bricout, A. Sayede, F. Hapiot, S. Tilloy, E. Monflier
   ChemSusChem 1 (2008) 631-636.

6. Hydroformylation of 1-Octene in Supercritical Carbon Dioxide : Can Alkylation of Arylphosphines with tertio-butyl Groups Lead to Soluble and Active Catalytic Systems?

   A. Galia, A. Cipollina, G. Filardo, O. Scialdone, M. Ferreira, E. Monflier,
   J. of Supercritical Fluids 46 (2008) 63-70.

7. Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with Rhodium Alkyl P-donor Ligands Using a Peracetylated β-Cyclodextrin as Solubiliser.

   C. Tortosa Estorach, M. Giménez-Pedrós, A.M. Masdeu-Bultó, A.D. Sayede, E. Monflier,
   Eur. J. Inorg. Chem. (2008) 2659-2663.

8. Rhodium-catalyzed Hydroformylation Promoted by Modified Cyclodextrins : Current Scope and Future Developments.

   F. Hapiot, L. Leclercq, N. Azaroual, S. Fourmentin, S. Tilloy, E. Monflier,
   Current Organic Synthesis 15 (2008) 162-172.

9. Fine tuning of sulfoalkylated cyclodextrin structures to improve their mass-transfer properties in an aqueous biphasic hydroformylation reaction.

   D. Kirschner, M. Jaramillo, T. Green, F. Hapiot, L. Leclercq, H. Bricout, E. Monflier,
   J. Mol. Catal. A.: Chem. 286 (2008) 11-20.

10. Biphasic Aqueous Organometallic Catalysis Promoted by Cyclodextrins: How to Design the Water-Soluble Phenylphosphane to Avoid Interaction with Cyclodextrin.

    M. Ferreira, H. Bricout, A. Sayede, A. Ponchel, S. Fourmentin, S. Tilloy, E. Monflier,
    Adv. Synth. Catal. 305 (2008) 609-618.

11. Chemically modified cyclodextrins adsorbed on Pd/C particles : New opportunities to generate highly chemo- and stereoselective catalysts for Heck reaction.

    A. Cassez, N. Kania, F. Hapiot, S. Fourmentin, E. Monflier, A. Ponchel,
    Catal. Commun. 9 (2008) 1346-1351.

12. Methylated Cyclodextrins : an efficient protective agent in water for zerovalent ruthenium nanoparticles and a supramolecular shuttle in alkene and arene hydrogenation reactions.

    A. Nowicki-Denicourt, A. Ponchel, E. Monflier, A. Roucoux,
    Dalton Trans. (2007) 5714-5719.

13. Catalytic hydrogen storage in cerium nickel and zirconium (or aluminium) mixed oxides.

    L. Jalowiecki-Duhamel, J. Carpentier, A. Ponchel
    Int. J. Hydrogen Energy 32 (2007) 2439-2444.

14. Complexation of phosphine ligands with peracetylated-β-cyclodextrin in supercritical carbon dioxide : spectroscopic determination of equilibrium constants.

    A. Galia, E. C. Navarre, O. Scialdone, M. Ferreira, G.Filardo, S. Tilloy, E. Monflier,
    J. Phys. Chem. B 111 (2007) 2573-2578.

15. First example of self-assembled supramolecular bidentate ligands for aqueous organometallic catalysis.

    C. Machut, J. Patrigeon, S. Tilloy, H. Bricout, F. Hapiot, E. Monflier,
    Angew. Chem. Int. Ed. 46 (2007) 3040-3042.

16. Aqueous organometallic catalysis promoted by cyclodextrins. Can surface tension measurements explain the efficiency of chemically modified cyclodextrins ?.

    L. Leclercq, H. Bricout, S. Tilloy, E. Monflier,
    J. Colloid Interface Sci. 307 (2007) 481-487.

17. A versatile liposome/cyclodextrin supramolecular carrier for drug delivery through the blood brain barrier.

    C. Machut-Binkowski, F. Hapiot, R. Cecchelli, P. Martin, E. Monflier
    J. Incl. Phenom. 57 (2007) 567-572.

18. Solubilisation of chlorinated solvents by cyclodextrin derivatives. A study by static headspace gas chromatochraphy and molecular modelling.

    S. Fourmentin, M. Outirite, P. Blach, D. Landy, A. Ponchel, E. Monflier, G. Surpateanu,
    J. Hazard. Mater. B 141 (2007) 92-97.

19. Water-soluble triphenylphosphane-3,3',3’''tricarboxylate (m-TPPTC) ligand and methylated cyclodextrins : a new combination for biphasic rhodium catalyzed hydroformylation of highers olefins.

    S. Tilloy, F. Hapiot, D. Landy, S. Fourmentin, V. Michelet, J. P. Genêt, E. Monflier,
    Adv. Synth. Catal. 348 (2006) 1547-1552.

20. Cyclodextrins as supramolecular host for organometallic complexes.

    F. Hapiot, S. Tilloy, E. Monflier,
    Chem. Rev. 106 (2006) 767-781.

21. Improvement of the dopant compatibility in a chiral LC mixture by structural modification of lanthanide complexes.

    F. Hapiot
    Liquid Crystals 33 (2006) 921-927.

22. Eco-efficient catalytic hydrodechloration of carbon tetrachloride in aqueous cyclodextrin solutions.

    A. Cassez, A. Ponchel, H. Bricout, S. Fourmentin, D. Landy, E. Monflier,
    Catal. Lett. 108 (2006) 209-214.

23. Methylated β-cyclodextrin as P-gp modulators for delivrance of doxorubicin across an in vitro model of blood-brain barrier.

    S. Tilloy, V. Monnaert, L. Fenart, H. Bricout, R. Cecchelli, E. Monflier
    Bioorg. Med. Chem. Lett. 16 (2006) 2154-2157.

24. Hydroformylation of 1-decene in aqueous medium catalyzed by rhodium/alkyl sulfonated diphosphines system in the presence of methylated β-cyclodextrins. How the flexibility of the diphosphine backbone influences the regioselectivity.

    S. Tilloy, G. Crowyn, E. Monflier, P. W. N. M. van Leeuwen, J. N. H. Reek,
    New. J. Chem. 30 (2006) 377-383.

25. Host–guest inclusion complexes between peracetylated β-cyclodextrin and diphenyl(4-phenylphenyl) phosphine : Computational studies.

    A. D. Sayede, A. Ponchel, G. Filardo, A. Galia, E. Monflier,
    J. Mol. Struct. THEOCHEM 777 (2006) 99-106.

26. Heptakis(2,3-di-O-methyl-6-O-sulfopropyl)-β-cyclodextrin : a genuine supramolecular carrier for the Aqueous Organometallic Catalysis.

    D. Kirschner, T. Green, F. Hapiot, S. Tilloy, L. Leclercq, H. Bricout, E. Monflier,
    Adv. Synth. Catal. 348 (2006) 379-386.

27. Supramolecular trapping of phosphanes by cyclodextrins: A general approach to generate phosphane coordinatively unsaturated organometallic complexes.

    C. Binkowski-Machut, M. Canipelle, H. Bricout, S. Tilloy, F. Hapiot, E. Monflier,
    Eur. J. Inorg. Chem. (2006) 1611-1619.

28. Peracetylated β-cyclodextrin as solubilizer of arylphosphines in supercritical carbon dioxide.

    G. Filardo, M. Di Blasi, A. Galia, A. Ponchel, H. Bricout, A. D. Sayede, E. Monflier,
    J. of Supercritical Fluids 36 (2006) 173-181.

29. Supramolecular shuttle and protective agent: a multiple role of methylated cyclodextrins in the chemoselective hydrogenation of benzene derivatives with ruthenium particles.

    A. Nowicki, Y. Zhang, B. Léger, J.P. Rolland, H. Bricout, E. Monflier, A. Roucoux, Chem. Commun. (2006) 296-298.

30. How cyclodextrins can mask their toxic effect on the blood-brain barrier.

    C. Binkowski-Machut, F. Hapiot, P. Martin, R. Cecchelli, E. Monflier
    Bioorganic and Medicinal Chemistry Letters 16 (2006) 1784-1787.

31. Unexpected multi-functional effects of methylated cyclodextrins in palladium charcoal-catalyzed Suzuki-Miyaura reaction.

    A. Cassez, A. Ponchel, F. Hapiot, E. Monflier, Org. Lett. 8 (2006) 4823-4826.

32. Rhodium complexes non-covalently bound to cyclodextrins: Novel water-soluble supramolecular catalysts for the biphasic hydroformylation of higher olefins.

    B. Sueur, L. Leclercq, M. Sauthier, Y. Castanet, A. Mortreux, H. Bricout, S. Tilloy, E. Monflier,
    Chem. Eur. J. 11 (2005) 6228-6236.

33. Substrate-selective aqueous organometallic catalysis. How small water-soluble organic molecules enhance the supramolecular discrimination.

    C. Torque, B. Sueur, J. Cabou, H. Bricout, F. Hapiot, E. Monflier,
    Tetrahedron 61 (2005) 4811-4817.

34. Sulfobutyl ether-β-cyclodextrins : Promising supramolecular carriers for aqueous organometallic catalysis.

    P. Blach, D. Landy, S. Fourmentin, G. Surpateanu, H. Bricout, A. Ponchel, F. Hapiot, E. Monflier,
    Adv. Synth. Catal. 347 (2005) 1301-1307.

35. Evidence of Self-inclusion Phenomenon for a New Class of Mono-substituted Alkylammonium-β-Cyclodextrins.

    C. Binkowski, F. Hapiot, V. Lequart, P. Martin, E. Monflier
    Org. Biomol. Chem. 3 (2005) 1129-1133.

36. Complexation of monosulfonated triphenylphosphine with chemically modified β-cyclodextrins : Effect of substituents on the stability of inclusion complexes.

    M. Canipelle, S. Tilloy, A. Ponchel, H. Bricout, E. Monflier
    J. Inclusion Phenom 51 (2005) 79-85.

37. Sulfonated Xantphos ligand and methylated cyclodextrin: a winning combination for rhodium catalysed hydroformylation of higher olefins in aqueous medium.

    L. Leclercq, F. Hapiot, S. Tilloy, K. Ramkisoensing, J. N. H. Reek, P. W. N. M. van Leeuwen, E. Monflier,
    Organometallics 24 (2005) 2070-2075.

38. Adamantoylated monosaccharides: new compounds for modification of cyclodextrin-containing material properties.

    C. Binkowski, V. Lequart, F. Hapiot, S. Tilloy, R. Cecchelli, E. Monflier, P. Martin
    Carbohydrate Research 340 (2005) 1461-1468.

39. Two-phase hydroformylation of higher olefins using randomly methylated β-cyclodextrin as mass transfer promoter : A smart solution for preserving the catalytic properties of the rhodium/trisulfonated triphenylphoshine catalytic system.

    L. Leclercq, M. Sauthier, Y. Castanet, A. Mortreux, H. Bricout, E. Monflier,
    Adv. Synth. Catal. 347 (2005) 55-59.

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