
Frederic Hapiot
received his Ph.D. from the University of Lille (France) in 1994 for his contribution to asymmetric catalysis research. He was promoted Associate Professor in 1995 at the University of Artois (France) where he studied liquid crystals and host-guest chemistry in the group of Eric Monflier. There, he completed his habilitation in 2006. In 2009, he moved to Florence (ICCOM, Italy) in the group of Maurizio Peruzzini. He became full Professor at the University of Artois in 2010. His current research is focused on design and characterization of supramolecular systems for molecular recognition and biphasic catalysis.
orcid.org/0000-0002-4394-8665
Publications 2021:
- «Cyclodextrins: a New and Effective Class of Co-Modulators for Aqueous Zirconium-MOF Syntheses»
G. Hoyez, J. Rousseau, C. Rousseau, S. Saitzek, J. King, P. Ágota Szilágyi, C. Volkringer, T. Loiseau, F. Hapiot, E. Monflier, A. Ponchel
CrystEngComm. 2021, 23, 2764 - 2772 - doi: 10.1039/D1CE00128K
Publications 2020:
- «One-pot two-steps synthesis of hydroxymethylated unsaturated VHOSO and its application to the synthesis of biobased polyurethanes»
K. Cousin, B. Quienne, J. Pinaud, S. Caillol, E. Monflier, F. Hapiot
Eur. J. Lipid Sci. Technol. 2020, 122, 2000158 - doi: 10.1002/ejlt.202000158
- «Particle size effect in the mechanically assisted synthesis of β-cyclodextrin mesitylene sulfonate»
S. Menuel, S. Saitzek, E. Monflier, F. Hapiot
Beilstein Journal of Organic Chemistry, 2020, 16, 2598-2606 - doi: 10.3762/bjoc.16.211
- «Selective ruthenium-catalyzed hydroaminomethylation of unsaturated oleochemicals»
K
. Cousin, F. Hapiot, E. Monflier
Eur. J. Lipid Sci. Technol. 2020, 122, 1900131 - doi: 10.1002/ejlt.201900131
Publications 2019:
- «Hydrogenation of hydrophobic substrates catalyzed by gold nanoparticles embedded in Tetronic/cyclodextrin-based hydrogels»
M. Chevry, S. Menuel, B. Léger, S. Noël, E. Monflier, F. Hapiot
New. J. Chem. 2019, 43, 9865-9872 - doi: 10.1039/c8nj06081a
- «One pot synthesis of aminohydroxylated triglycerides under aqueous biphasic conditions»
K. Cousin, T. Vanbésien, E. Monflier, F. Hapiot
Catal. Commun. 2019, 125, 37-42 - doi: 10.1016/j.catcom.2019.03.018
Publications 2018:
- «Pillar[5]arenes as supramolecular hosts in aqueous biphasic rhodium-catalyzed hydroformylation of long alkyl-chain alkenes»
M. Benatmane, K. Cousin, N. Laggoune, S. Menuel, E. Monflier, P. Woisel, F. Hapiot, J. Potier
ChemCatChem, 2018, 10, 5306-5313 - doi: 10.1002/cctc.201801551
- «Amines as Effective Ligands in Iridium-Catalyzed Decarbonylative Dehydration of Biosourced Substrates»
J. Ternel, B. Léger, E. Monflier, F. Hapiot
Catal. Sci. Technol. 2018, 8, 3948-3953 - doi: 10.1039/C8CY00621K
- «Hydroaminomethylation of oleochemicals: a comprehensive overview»
T. Vanbésien, J. Le Nôtre, E. Monflier, F. Hapiot
Eur. J. Lipid Sci. Technol., 2018, 120, 1700190 - doi: 10.1002/ejlt.201700190
Publications 2017:
- «Water-soluble Phosphane-Substituted Cyclodextrin as Effective Bifunctional Additive in Hydroformylation of Higher Olefins»
J. Leblond, J. Potier, S. Menuel, H. Bricout, C. Machut-Binkowski, D. Landy, S. Tilloy, E. Monflier, F. Hapiot
Catal. Sci. Technol. 2017, 7, 3823 – 3830 - doi: 10.1039/C7CY01108C
- «Hydroformylation of alkenes in a planetary ball mill: from additive-controlled reactivity to supramolecular control of regioselectivity»
K. Cousin, S. Menuel, E. Monflier, F. Hapiot
Angew. Chem. Int. Ed. 2017, 56, 10564-10568 - doi: 10.1002/anie.201705467
- «Hydroaminomethylation/hydrohydroxymethylation sequence for the one pot synthesis of aminohydroxytriglycerides»
T. Vanbesien, E. Monflier, F Hapiot
Green Chem. 2017, 19, 1940-1948 - doi: 10.1039/C7GC00061H
- «Unconventional approaches involving cyclodextrin-based self-assembly driven processes for the conversion of organic substrates in aqueous biphasic catalysis»
F. Hapiot, E. Monflier
Catalysts, 2017, 7, 173 - doi: 10.3390/catal7060173
- «Catalysis in cyclodextrin-based unconventional reaction media: recent developments and future opportunities»
F. Hapiot, S. Menuel, M. Ferreira, B. Léger, H. Bricout, S. Tilloy, E. Monflier
ACS Sustainable Chem. Eng. 2017, 5, 3598-3606 - doi: 10.1021/acssuschemeng.6b02886
- «Tetronics/cyclodextrin-based hydrogels as catalyst-containing media for the hydroformylation of higher olefins»
M. Chevry, T. Vanbesien, S. Menuel, E. Monflier, F Hapiot
Catal. Sci. Technol., 2017, 7, 114-123 - doi: 10.1039/C6CY02070D
Publications 2016 :
- «Rhodium-catalyzed one pot synthesis of hydroxymethylated triglycerides»
T. Vanbésien, E. Monflier, F. Hapiot
Green Chem 2016,18, 6687-6694 - doi: 10.1039/C6GC02706G
- «Conjugated dienyl derivatives by green bisallylic substitution: synthetic and mechanistic insights»
C. Cazorla, M. Billamboz, C. Chevrin-Villette, F. Hapiot, E. Monflier, C. Len
ChemCatChem 2016, 8, 2321-2328 - doi: 10.1002/cctc.201600343
- «Cyclodextrins as Effective Additives in AuNPs-Catalyzed Reduction of Nitrobenzene Derivatives in a Ball-Mill»
S. Menuel, B. Léger, A. Addad, E. Monflier, F. Hapiot
Green Chem. 2016, 18, 5500–5509 - doi: 10.1039/C6GC00770H
- «A self-emulsifying catalytic system for the aqueous biphasic hydroformylation of triglycerides»
T. Vanbésien, A. Sayede, E. Monflier, F. Hapiot
Cat Sci Technol 2016, 6, 3064 - 3073 - doi: 10.1039/C5CY01758K
- «Greener Paal-Knorr pyrrole synthesis by mechanical activation»
L. Akelis, J. Rousseau, R. Juskenas, J. Dodonova, C. Rousseau, S. Menuel, D. Prevost, S. Tumkevičius, E. Monflier, F. Hapiot
Eur. J. Org. Chem. 2016, 31-35 - doi: 10.1002/ejoc.201501223
- «Hydroformylation of vegetable oils: More than 50 years of technical innovation, successful research and development»
T. Vanbésien, E.Monflier, F. Hapiot
Eur. J. Lipid Sci. Technol., 2016, 118, 26-35 - doi: 10.1002/ejlt.201500196
- «Cyclodextrins Modified by Metal-Coordinating Groups for Aqueous Organometallic Catalysis: What remains to be done?»
S. Tilloy, H. Bricout, S. Menuel, F. Hapiot and E. Monflier
Current Organocatalysis volume 3, pages 24-31, 2016
doi: 10.2174/2213337202666150618192947
Publications 2015: - «Cyclodextrin-based PNN supramolecular assemblies: a new class of pincer-type ligands for aqueous organometallic catalysis»
S. Menuel, E. Bertaut, E. Monflier, F. Hapiot
Dalton Trans. 2015, 44, 13504–13512
HOT article
- doi: 10.1039/C5DT01825K
- «Recent developments in cyclodextrin-mediated aqueous biphasic hydroformylation and Tsuji-Trost reactions»
F. Hapiot, S. Menuel, H. Bricout, S. Tilloy, E. Monflier
Appl. Organometal. Chem. 2015, 29, 580–587 - doi: 10.1002/aoc.3340
- «Selective secondary face modification of cyclodextrins by mechanosynthesis»
S. Menuel, B. Doumert,; S. Saitzek, A. Ponchel, L. Delevoye, E. Monflier, F. Hapiot
J. Org. Chem. 2015, 80, 6259-6266 - doi: 10.1021/acs.joc.5b00697
- «Supramolecular emulsifiers in biphasic catalysis: the substrate drives its own transformation»
T. Vanbésien, F. Hapiot, E. Monflier
ACS Catal. 2015, , 5, 4288-4292 - doi: 10.1021/acscatal.5b00861
- «Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands»
K. Sordakis, A. Guerriero, H. Bricout, M. Peruzzini, P. J. Dyson, E. Monflier, F. Hapiot, L. Gonsalvi, G. Laurenczy
Inorganica Chimica Acta 2015, 431, 132–138
- doi: 10.1016/j.ica.2014.10.034
- «Catalytic decarbonylation of biosourced substrates»
J. Ternel, T. Lebarbé, E. Monflier, F. Hapiot
ChemSusChem 2015, 8, 1585-1592 - doi: 10.1002/cssc.201500214
- «Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation»
J. Potier, A. Guerriero, S. Menuel, E. Monflier, Peruzzini, F. Hapiot, L. Gonsalvi
Catal. Com. 2015, 63, 74-78 - doi: 10.1016/j.catcom.2014.11.030
- «Thermoresponsive self-assembled cyclodextrin-end-decorated PNIPAM for aqueous catalysis»
J. Potier, S. Menuel, J. Lyskawa, D.Fournier, F. Stoffelbach, E. Monflier, P. Woisel, F. Hapiot
Chem. Commun., 2015, 51, 2328-2330 - doi: 10.1039/c4cc09052g
Publications 2014: - «Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis»
J. Potier, S. Menuel, D. Mathiron, V. Bonnet, F. Hapiot, E. Monflier
Beilstein J. Org. Chem. 2014, 10, 2642-2648 -.doi: 10.3762/bjoc.10.276
- «Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-biaryl Sulfonated Phosphines in Aqueous Solution»
A. Guerriero, H. Bricout, K. Sordakis, M. Peruzzini, E. Monflier, F. Hapiot, G. Laurenczy, L. Gonsalvi
ACS Catalysis 2014, 4, 3002−3012 - doi: 10.1021/cs500655x
- «Synergetic effect of randomly methylated ß-cyclodextrin and supramolecular hydrogel in Rh-catalyzed hydroformylation of higher olefins»
J. Potier, S. Menuel, E. Monflier, F. Hapiot
ACS Catalysis 2014, 4, 2342-2346 - doi: 10.1021/cs5004883
- «Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis»
F. Hapiot, H. Bricout, S. Menuel, S. Tilloy, E. Monflier
Catal. Sci. Technol., 2014, 4, 1899-1908 - doi: 10.1039/C4CY00005F
- «Multifunctional cyclodextrin-based N,N-bidentate ligands for aqueous Heck arylation»
J.Potier, S.Menuel, J.Rousseau, S.Tumkevicius, F.Hapiot, E.Monflier
Applied Catalysis A:General, 2014, 479, 1-8 - doi: 10.1016/j.apcata.2014.04.021
- «Limits of the Inversion Phenomenon in Triazolyl-Substituted β-Cyclodextrin Dimers»
J. Potier, S. Menuel, N. Azaroual, E. Monflier, F. Hapiot
Eur. J. Org. Chem. 2014 -1547-1556 - doi: 10.1002/ejoc.201301681
- «Effective catalytic hydrogenation of Fatty Acids Methyl Esters by aqueous rhodium(0) nanoparticles stabilized by cyclodextrin-based polymers»
S. Noël, B. Léger, A. Ponchel, F. Hapiot, E. Monflier Chem. Eng. Trans., 2014, 37, 337-342 - doi: 10.3303/CET1437057
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