
Sébastien Tilloy
was born in 1972 in Douai (North, France). He received his
Ph.D degree in 1998
from the University of Artois
under the supervision of Pr E. Monflier.
In 2000, he became «Maître
de Conférences» at the University of Artois where
he completed his Habilitation
in 2004. In 2005,
he spent six months as a postdoctoral
position at the University of
Amsterdam (Netherlands) with Pr.
Piet van Leeuwen and Pr. Joost Reek. In 2006, he was promoted Professor. His research
interests are centred
on he cyclodextrins and more
specifically on their supramolecular implications
in the fields of aqueous biphasic catalysis in the presence of organometallic catalysis. These last years were devoted to better understand the behavior of cyclodextrins in these catalytic processes especially by spectroscopic studies of inclusion complexes between cyclodextrins and water-soluble phosphines and / or organometallic complexes.
He is the author of 106 international scientific publications and more than 40 oral or poster presentations.
orcid.org/0000-0002-3494-4734
Bibliometric indicators
(ISI Web of Knowledge, May 23, 2023) : |
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- All publications (pdf), August, 2017
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Publications 2025:
- «Rhodium/Trialkylamines Catalyzed Reductive Hydroformylation in Ionic Liquid/Heptane Medium: An Unexpected Concept for Catalyst Recycling in Batch and Continuous Flow Processes»
A. El Mouat, W. Abdallah, J. Ternel, M. Ferreira, H. Bricout, A.J. Vorholt, H. Stieber, S. Stoertte, E. Monflier, M. Lahcini, S. Tilloy
ChemSusChem 2025, e202401384 - doi: 10.1002/cssc.202401384
Publications 2024:
- «The role of cyclodextrins in the acceleration of the reaction rate in a biphasic hydroformylations»
K. E. Naße, F.S. Heinen, N. Pawlowsky, M. Schrimpf, E. Monflier, S. Tilloy, W. Leitner, A.J. Vorholt
Chem. Eng. J. 2024, 497, 154114 - doi: 10.1016/j.cej.2024.154114
- «Aqueous biphasic hydroformylation and hydroaminomethylation assisted by cyclodextrins: From benchtop to industrial perspective»
M. Ferreira, H. Bricout, T.F.H. Roth, T. Seidensticker, S. Tilloy, E. Monflier
Catal. Today 2024, 442, 114951 - doi: 10.1016/j.cattod.2024.114951
- «Rhodium-Catalyzed Reductive Hydroformylation of Polyunsaturated Vegetable Oils Assisted by Triethylamine/N-methylimidazole Ligands Combination»
W. Abdallah, M. Ferreira, C. Becquet, J. Ternel, H. Bricout, E. Monflier, S. Tilloy
ChemCatChem 2024, 0, e202401677 - doi: 10.1002/cctc.202401677
- « Stereoisomers Are Not Machine Learning’s Best Friends»
G. Tahıl, F. Delorme, D. Le Berre, E. Monflier, A. Sayede, and S. Tilloy
J. Chem. Inf. Model, 2024, 64, 14, 5451–5469. - doi: 10.1021/acs.jcim.4c00318
Publications 2023:
- «Continuous production of amines directly from alkenes via cyclodextrin-mediated hydroaminomethylation using only water as the solvent»
T. Friedrich Hubertus Roth, R. Evertz, N. Kopplin, S. Tilloy, E. Monflier, D. Vogt and T. Seidensticker
Green Chem, 2023, 25, 3680 - doi: 10.1039/D2GC04847G
- «Curated dataset of association constants between a cyclodextrin and a guest for machine learning.»
G. Tahıl, F. Delorme, D. Le Berre, E. Monflier, A. Sayede, S. Tilloy
Chemical Data Collections Volume 45, June 2023, 101022 - doi: 10.1016/j.cdc.2023.101022
- «Exploiting poly(ε-caprolactone) grafted from hydrohydroxymethylated sunflower oil as biodegradable coating material of water-soluble fertilizers»
A. El Mouat, T. El Assimi, M. Raihane, J. Ternel, H. Bricout, E. Monflier, S. Tilloy, M. Lahcini
Progress in Organic Coatings 179 (2023) 107513 - doi: 10.1016/j.porgcoat.2023.107513
Publications 2022:
- «Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions»
D.N. Gorbunov, M.V. Nenasheva, M.V. Terenina, Yu. S Kardasheva, E.R. Naranov, A.L. Bugaev, A.V. Soldatov, A.L. Maximov, S. Tilloy, E. Monflier, E.A. Karakhanov
Appl. Catal. A 2022, 647, 118891 - doi: 10.1016/j.apcata.2022.118891
- «Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes»
C. Becquet, M. Ferreira, H. Bricout, B. Quienne, S. Caillol, E. Monflier and S. Tilloy
Green Chemistry, 2022, 24, 7906–7912 - doi: 10.1039/D2GC02534E
- «Promising Recyclable Ionic Liquid-Soluble Catalytic System for Reductive Hydroformylation»
A. El Mouat, C. Becquet, J. Ternel, M. Ferreira, H. Bricout, E. Monflier, M. Lahcini, and S. Tilloy
ACS Sustainable Chem. Eng, 10, 34, 11310–11319 - doi : 10.1021/acssuschemeng.2c03302
- «Interesterification of triglycerides with methyl acetate for biodiesel production using a cyclodextrin-derived SnO@γ-Al2O3 composite as heterogeneous catalyst»
C. Prestigiacomo, M. Biondo, A. Galia, E. Monflier, A. Ponchel, D. Prevost, O. Scialdone, S. Tilloy, R. Bleta
Fuel 321 (2022) 124026 - doi: 10.1016/j.fuel.2022.124026
- «Unnatural cyclodextrins can be accessed from enzyme-mediated dynamic combinatorial libraries»
D. Larsen, M. Ferreira, S. Tilloy, E. Monflier, S.R. Beeren
Chem. Commun. 2022, 58, 2287-2290 - doi : 10.1039/D1CC06452E
This article is part of the themed collection: Chemical Communications HOT Articles 2022
Publications 2021:- «Reductive Hydroformylation of Isosorbide Diallyl Ether»
J. Ternel, A. Lopes, M. Sauthier, C. Buffe, V. Wiatz, H. Bricout, S. Tilloy, and E. Monflier Molecules, 2021, 26, 7322 - doi: 10.3390/molecules26237322
- «Hydrohydroxymethylation of Ethyl Ricinoleate and Castor Oil»
C. Becquet, F. Berche, H. Bricout, E. Monflier, S. Tilloy
ACS Sustain Chem Eng, 2021, 9, 9444−9454 -
doi: 10.1021/acssuschemeng.1c02924
- «Asymmetric hydrogenation of ethyl pyruvate over aqueous dispersed Pt nanoparticles stabilized by a cinchonidine-functionalized β-cyclodextrin»
S. Noël, E. Caronia, H. Bricout, I. Chena Tichá, S. Menuel, A. Ponchel, S. Tilloy, A. Galia, E. Monflier, J. Jindřich, B. Léger
Catal. Commun. 2021, 150, 106272 - doi: 10.1016/j.catcom.2020.106272
- «Aqueous biphasic hydroaminomethylation enabled by methylated cyclodextrins: Sensitivity analysis for transfer into a continuous process »
K. Künnemann, D. Weber, C. Becquet, S. Tilloy, E. Monflier, T. Seidensticker, D. Vogt
ACS Sustain. Chem. Eng. 2021, 9, 273-283. - doi:: 10.1021/acssuschemeng.0c07125
- «Epimerization of Isosorbide Catalyzed by Homogeneous Ruthenium-Phosphine Complexes: a New Step towards an Industrial Process»
T. Vanbésien, T. Delaunay, V. Wiatz, S. Bigot, H. Bricout, S. Tilloy, E. Monflier
Inorg. Chim. Acta 2021, 515, 120094 - doi: 10.1016/j.ica.2020.120094
Publications 2020:
- «Anionic Amphiphilic Cyclodextrins bearing Oleic Grafts for the Stabilization of Ruthenium Nanoparticles Efficient in Aqueous Catalytic Hydrogenation»
A. Cocq, B. Léger; S. Noel; H. Bricout; F. Pilard; S. Tilloy; E. Monflier
ChemCatChem 2020, 12, 1013-1018 - doi: 10.1002/cctc.201901837
- «Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins»
K. U. Künnemann, L. Schurm, D. Lange, T. Seidensticker, S. Tilloy, E. Monflier, D. Vogt and J. M. Dreimann
Green Chem, 2020, 22, 3809-3819 - doi: 10.1039/D0GC00820F
- «Multiscale Structure of Starches Grafted with Hydrophobic Groups: A new Analytical Strategy»
C. Volant, A. Gilet, F. Beddiaf, M. Collinet-Fressancourt, X. Falourd, N. Descamps, V. Wiatz, H. Bricout, S. Tilloy, E. Monflier, C. Quettier, A. Mazzah, A. Rolland-Sabate
Molecules 2020, 25, 2827 - doi:10.3390/molecules25122827
- «New Lipidyl-Cyclodextrins Obtained by Ring Opening of Methyl Oleate Epoxide Using Ball Milling»
E. Oliva, D. Mathiron, S. Rigaud, E. Monflier, E. Sevin, H. Bricout, S. Tilloy, F. Gosselet, L. Fenart, V. Bonnet, S. Pilard and F. Djedaini-Pilard
Biomolecules, 2020, 10(2), 339 - doi: 10.3390/biom10020339
- «Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins»
A. Cocq, H. Bricout, F. Djedaïni-Pilard, S. Tilloy, E. Monflier
Catalysts 2020, 10, 56 - doi: 10.3390/catal10010056
- «Fréchet-type metallodendrons with N,P-iminophosphine Rh(I) complexes at the focal point: Synthesis and evaluation in the hydroformylation of 1-octene
C. Williams, M. Ferreira, S. Tilloy, E. Monflier, S. F. Mapolie, G. S. Smith
Inorg Chim Acta, 2020, 502, 119341 - doi: 10.1016/j.ica.2019.119341
Publications 2019:
- «Highly Water-Soluble Amphiphilic Cyclodextrins bearing Branched and Cyclic Oleic Grafts»
A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
Eur. J. Org. Chem. 2019, 4863-4868 - doi : 10.1002/ejoc.201900789
- «First evidence of cyclodextrin inclusion complexes in a deep eutectic solvent»
T. Moufawad, L. Moura, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M. Costa Gomes, D. Landy, S. Fourmentin
ACS SUSTAIN CHEM ENG, 2019, 7, 6, 6345–6351 - doi: 10.1021/acssuschemeng.9b00044
- «Synthesis of 2-Hydroxydodecyl Starch Ethers: Importance of the Purification Process»
A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier, and S. Tilloy
Ind. Eng. Chem. Res. 2019, 58, 7, 2437-2444 - doi: 10.1021/acs.iecr.8b02605
- «Oleic Acid Based Cyclodextrins for the Development of New Hydrosoluble Amphiphilic Compounds»
A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
Eur. J. Org. Chem. 2019 , 1236–1241 - doi: 10.1002/ejoc.201801609
Publications 2018:- «Robust Mesoporous CoMo/γ-Al2O3 Catalysts from Cyclodextrin-Based Supramolecular Assemblies for Hydrothermal Processing of Microalgae: Effect of the Preparation Method»
R. Bleta, B. Schiavo, N. Corsaro, P. Costa, A. Giaconia, L. Interrante, E. Monflier, G. Pipitone, A. Ponchel, S. Sau, O. Scialdone, S. Tilloy, A. Galia
ACS Appl. Mater. Interfaces 2018, 10(15), 12562-12579 - doi: 10.1021/acsami.7b16185
- «New water-soluble Schiff base ligands based on β-cyclodextrin for aqueous biphasic hydroformylation reaction»
M. Dauchy, M. Ferreira, J. Leblond, H. Bricout, S. Tilloy, G. S. Smith, E. Monflier
Pure Appl. Chem., 2018, 90(5), 845-855 -. doi: 10.1515/pac-2017-1205
- «Unconventional media and technologies for starch etherification and esterification»
A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier and S. Tilloy
Green Chem., 2018, 20, 1152–1168 - doi: 10.1039/C7GC03135A
Publications 2017: - «Deep eutectic solvents: a promising medium for Volatile Organic Compounds absorption»
L. Moura, T. Moufawad, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M.F. Costa Gomes, D. Landy, S. Fourmentin
Environ. Chem. Lett. 2017, 15(4), 747-753 - doi: 10.1007/s10311-017-0654-y
- «Water-soluble Phosphane-Substituted Cyclodextrin as Effective Bifunctional Additive in Hydroformylation of Higher Olefins»
J. Leblond, J. Potier, S. Menuel, H. Bricout, C. Machut-Binkowski, D. Landy, S. Tilloy, E. Monflier, F. Hapiot
Catal. Sci. Technol. 2017, 7, 3823 – 3830 - doi: 10.1039/C7CY01108C
- «Enhance the rheological and mechanical properties of clayey materials by adding starches»
G. Alhaik, M. Ferreira, V. Dubois, E. Wirquin, S. Tilloy, E. Monflier, G. Aouad
Constr. Build Mater., 2017, 139, 602-610 - doi : 10.1016/j.conbuildmat.2016.11.130
- «Catalysis in cyclodextrin-based unconventional reaction media: recent developments and future opportunities»
F. Hapiot, S. Menuel, M. Ferreira, B. Léger, H. Bricout, S. Tilloy, E. Monflier
ACS Sustainable Chem. Eng. 2017, 5, 3598-3606 - doi: 10.1021/acssuschemeng.6b02886
- «Transition metal complexes coordinated by water soluble phosphane ligands: How cyclodextrins can alter the coordination Sphere?»
M. Ferreira, H. Bricout, S. Tilloy, E. Monflier
Molecules 2017, 22, 140 - doi: 10.3390/molecules22010140
Publications 2016 :
- «Cyclodextrins as emerging therapeutic tools in the treatment of cholesterol-associated vascular and neurodegenerative diseases»
C. Coisne, S. Tilloy, E. Monflier, D. Wils, L. Fenart, F. Gosselet
Molecules, 2016, 21, 1748 - doi: 10.3390/molecules21121748
- «Ring Opening Polymerization of ε-Caprolactone in the Presence of wet β-Cyclodextrin: Effect of the Operative Pressure and of Water Molecules in the β-Cyclodextrin Cavity»
A. Galia, O. Scialdone, T. Spanò, M. Grazia Valenti, B. Grignard, P. Lecomte, E. Monflier, S. Tilloy and C. Rousseau
RSC Adv., 2016, 6, 90290-90299 - doi: 10.1039/C6RA20211J
- «Cleavage of Benzyl Phosphonium Salts as Efficient Bypass for Synthesis of Disulfonated Alkyldiphenylphosphanes Bearing an Oleum-Sensitive Alkyl Group»
J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
Eur. J. Org. Chem. 2016, 3322–3325 - doi: 10.1002/ejoc.201600555
- «Methylated β-cyclodextrins decrease cholesterol release in smooth muscle cells and aortic endothelial cells via ABCA1- and ABCG1-mediated process»
C. Coisne, D. Hallier-Vanuxeem, M-C. Boucau, J. Hachani, S. Tilloy, H. Bricout, E. Monflier, D. Wils, M. Serpelloni, X. Parissaux, L. Fenart, F. Gosselet
Frontiers in Physiology, section Lipidology, 2016, 7, 185 - doi: 10.3389/fphys.2016.00185
- «Cyclodextrins Modified by Metal-Coordinating Groups for Aqueous Organometallic Catalysis: What remains to be done?»
S. Tilloy, H. Bricout, S. Menuel, F. Hapiot and E. Monflier
Current Organocatalysis volume 3, pages 24-31, 2016
doi: 10.2174/2213337202666150618192947
Publications 2015:
- «Tetrasulfonated 1,2-Bis(diphenylphosphanyl)ethane as a Building Block for the Synthesis of Disulfonated Alkyldiphenylphosphanes»
J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
Eur. J. Org. Chem 2015, 5509–5512 - doi: 10.1002/ejoc.201500772
- «Recent developments in cyclodextrin-mediated aqueous biphasic hydroformylation and Tsuji-Trost reactions»
F. Hapiot, S. Menuel, H. Bricout, S. Tilloy, E. Monflier
Appl. Organometal. Chem. 2015, 29, 580–587 - doi: 10.1002/aoc.3340
- «Ruthenium-containing β-cyclodextrin polymer globules for the catalytic hydrogenation of biomass-derived furanic compounds»
R. Herbois, S. Noël, B. Léger, S. Tilloy, S. Menuel, A. Addad, B. Martel, A. Ponchel, E. Monflier Green Chem. 2015, 17, 2444 - 2454 - doi: 10.1039/C5GC00005J
- «Rhodium catalyzed hydroformylation assisted by cyclodextrins in biphasic medium: can sulfonated naphthylphosphanes lead to active, selective and recyclable catalytic species?»
M. Elard, J. Denis, M. Ferreira, H. Bricout, D. Landy, S. Tilloy, E. Monflier
Catalysis Today 247 (2015) 47–54 - doi: 10.1016/j.cattod.2014.06.002
- «Rhodium Catalyzed Hydroformylation of 1-Decene in Low Melting Mixtures Based on Various Cyclodextrins and N,N’-Dimethylurea»
M. Ferreira, F. Jérôme, H. Bricout, S. Menuel, D. Landy, S. Fourmentin, S. Tilloy, E. Monflier
Catal. Com., 2015, 63, 62-65 - doi : 10.1016/j.catcom.2014.11.001
Publications 2014: - «Synthesis and characterization of a new photoinduced switchable β-cyclodextrin dimer»
F. Hamon, C. Blaszkiewicz, M. Buchotte, E. Banaszak-Léonard, H. Bricout, S. Tilloy, E. Monflier, C. Cézard, L. Bouteiller, C. Len and F. Djedaini-Pilard
Beilstein J. Org. Chem. 2014, 10, 2874–2885 - doi: 10.3762/bjoc.10.304
- «Low melting mixtures based on β-cyclodextrin derivatives and N,N’-dimethylurea as solvents for sustainable catalytic processes»
F. Jerome, M. Ferreira, H. Bricout, S. Menuel, E. Monflier, S. Tilloy
Green Chem., 2014, 16 (8), 3876 - 3880 - doi: 10.1039/C4GC00591K
- «Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis»
F. Hapiot, H. Bricout, S. Menuel, S. Tilloy, E. Monflier
Catal. Sci. Technol., 2014, 4, 1899-1908 - doi: 10.1039/C4CY00005F
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