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Sébastien Tilloy was born in 1972 in Douai (North, France). He received his Ph.D degree in 1998 from the University of Artois under the supervision of Pr E. Monflier. In 2000, he became «Maître de Conférences» at the University of Artois where he completed his Habilitation in 2004. In 2005, he spent six months as a postdoctoral position at the University of Amsterdam (Netherlands) with Pr. Piet van Leeuwen and Pr. Joost Reek. In 2006, he was promoted Professor. His research interests are centred on he cyclodextrins and more specifically on their supramolecular implications in the fields of aqueous biphasic catalysis in the presence of organometallic catalysis. These last years were devoted to better understand the behavior of cyclodextrins in these catalytic processes especially by spectroscopic studies of inclusion complexes between cyclodextrins and water-soluble phosphines and / or organometallic complexes. He is the author of 106 international scientific publications and more than 40 oral or poster presentations.


Bibliometric indicators (ISI Web of Knowledge, May 23, 2023) :

  • All publications (pdf), August, 2017

Publications 2023:

  1. «Continuous production of amines directly from alkenes via cyclodextrin-mediated hydroaminomethylation using only water as the solvent»
    T. Friedrich Hubertus Roth, R. Evertz, N. Kopplin, S. Tilloy, E. Monflier, D. Vogt and T. Seidensticker
    Green Chem, 2023, 25, 3680
    - doi: 10.1039/D2GC04847G
    Voir aussi «Publications marquantes 2023»

  2. «Curated dataset of association constants between a cyclodextrin and a guest for machine learning.»
    G. Tahıl, F. Delorme, D. Le Berre, E. Monflier, A. Sayede, S. Tilloy
    Chemical Data Collections Volume 45, June 2023, 101022
    - doi: 10.1016/j.cdc.2023.101022

  3. «Exploiting poly(ε-caprolactone) grafted from hydrohydroxymethylated sunflower oil as biodegradable coating material of water-soluble fertilizers»
    A. El Mouat, T. El Assimi, M. Raihane, J. Ternel, H. Bricout, E. Monflier, S. Tilloy, M. Lahcini
    Progress in Organic Coatings 179 (2023) 107513
    - doi: 10.1016/j.porgcoat.2023.107513
    See «Publications marquantes 2023»

Publications 2022:

  1. «Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions»
    D.N. Gorbunov, M.V. Nenasheva, M.V. Terenina, Yu. S Kardasheva, E.R. Naranov, A.L. Bugaev, A.V. Soldatov, A.L. Maximov, S. Tilloy, E. Monflier, E.A. Karakhanov
    Appl. Catal. A 2022, 647, 118891
    - doi: 10.1016/j.apcata.2022.118891
    Voir aussi «Publications marquantes 2022»

  2. «Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes»
    C. Becquet, M. Ferreira, H. Bricout, B. Quienne, S. Caillol, E. Monflier and S. Tilloy
    Green Chemistry, 2022, 24, 7906–7912
    - doi: 10.1039/D2GC02534E
    See «Publications marquantes 2022»

  3. «Promising Recyclable Ionic Liquid-Soluble Catalytic System for Reductive Hydroformylation»
    A. El Mouat, C. Becquet, J. Ternel, M. Ferreira, H. Bricout, E. Monflier, M. Lahcini, and S. Tilloy
    ACS Sustainable Chem. Eng, 10, 34, 11310–11319
    - doi : 10.1021/acssuschemeng.2c03302
    See «Publications marquantes 2022»

  4. «Interesterification of triglycerides with methyl acetate for biodiesel production using a cyclodextrin-derived SnO@γ-Al2O3 composite as heterogeneous catalyst»
    C. Prestigiacomo, M. Biondo, A. Galia, E. Monflier, A. Ponchel, D. Prevost, O. Scialdone, S. Tilloy, R. Bleta
    Fuel 321 (2022) 124026
    - doi: 10.1016/j.fuel.2022.124026
    See «Publications marquantes 2022»

  5. «Unnatural cyclodextrins can be accessed from enzyme-mediated dynamic combinatorial libraries»
    D. Larsen, M. Ferreira, S. Tilloy, E. Monflier, S.R. Beeren
    Chem. Commun. 2022, 58, 2287-2290
    - doi : 10.1039/D1CC06452E
    See «Publications marquantes 2022»

    This article is part of the themed collection: Chemical Communications HOT Articles 2022

Publications 2021:

  1. «Reductive Hydroformylation of Isosorbide Diallyl Ether»
    J. Ternel, A. Lopes, M. Sauthier, C. Buffe, V. Wiatz, H. Bricout, S. Tilloy, and E. Monflier
    Molecules, 2021, 26, 7322 - doi: 10.3390/molecules26237322

  2. «Hydrohydroxymethylation of Ethyl Ricinoleate and Castor Oil»
    C. Becquet, F. Berche, H. Bricout, E. Monflier, S. Tilloy
    ACS Sustain Chem Eng, 2021, 9, 9444−9454 -
    doi: 10.1021/acssuschemeng.1c02924
    See also «Publications marquantes 2021»

  3. «Asymmetric hydrogenation of ethyl pyruvate over aqueous dispersed Pt nanoparticles stabilized by a cinchonidine-functionalized β-cyclodextrin»
    S. Noël, E. Caronia, H. Bricout, I. Chena Tichá, S. Menuel, A. Ponchel, S. Tilloy, A. Galia, E. Monflier, J. Jindřich, B. Léger
    Catal. Commun. 2021, 150, 106272
    - doi: 10.1016/j.catcom.2020.106272

  4. «Aqueous biphasic hydroaminomethylation enabled by methylated cyclodextrins: Sensitivity analysis for transfer into a continuous process »
    K. Künnemann, D. Weber, C. Becquet, S. Tilloy, E. Monflier, T. Seidensticker, D. Vogt
    ACS Sustain. Chem. Eng. 2021, 9, 273-283.
    - doi:: 10.1021/acssuschemeng.0c07125
    See also «Publications marquantes 2021»

  5.  «Epimerization of Isosorbide Catalyzed by Homogeneous Ruthenium-Phosphine Complexes: a New Step towards an Industrial Process»
    T. Vanbésien, T. Delaunay, V. Wiatz, S. Bigot, H. Bricout, S. Tilloy, E. Monflier
    Inorg. Chim. Acta 2021, 515, 120094
    - doi: 10.1016/j.ica.2020.120094

Publications 2020:

  1. «Anionic Amphiphilic Cyclodextrins bearing Oleic Grafts for the Stabilization of Ruthenium Nanoparticles Efficient in Aqueous Catalytic Hydrogenation»
    A. Cocq, B. Léger; S. Noel; H. Bricout; F. Pilard; S. Tilloy; E. Monflier
    ChemCatChem 2020, 12, 1013-1018
    - doi: 10.1002/cctc.201901837

  2. «Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins»
    K. U. Künnemann, L. Schurm, D. Lange, T. Seidensticker, S. Tilloy, E. Monflier, D. Vogt and J. M. Dreimann
    Green Chem, 2020, 22, 3809-3819
    - doi: 10.1039/D0GC00820F
    See «Publications marquantes 2020»

  3. «Multiscale Structure of Starches Grafted with Hydrophobic Groups: A new Analytical Strategy»
    C. Volant, A. Gilet, F. Beddiaf, M. Collinet-Fressancourt, X. Falourd, N. Descamps, V. Wiatz, H. Bricout, S. Tilloy, E. Monflier, C. Quettier, A. Mazzah, A. Rolland-Sabate
    Molecules 2020, 25, 2827
    - doi:10.3390/molecules25122827

  4. «New Lipidyl-Cyclodextrins Obtained by Ring Opening of Methyl Oleate Epoxide Using Ball Milling»
    E. Oliva, D. Mathiron, S. Rigaud, E. Monflier, E. Sevin, H. Bricout, S. Tilloy, F. Gosselet, L. Fenart, V. Bonnet, S. Pilard and F. Djedaini-Pilard
    Biomolecules, 2020, 10(2), 339
    - doi: 10.3390/biom10020339

  5. «Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins»
    A. Cocq, H. Bricout, F. Djedaïni-Pilard, S. Tilloy, E. Monflier
    Catalysts 2020, 10, 56
    - doi: 10.3390/catal10010056

  6. «Fréchet-type metallodendrons with N,P-iminophosphine Rh(I) complexes at the focal point: Synthesis and evaluation in the hydroformylation of 1-octene
    C. Williams, M. Ferreira, S. Tilloy, E. Monflier, S. F. Mapolie, G. S. Smith
    Inorg Chim Acta, 2020, 502, 119341
    - doi: 10.1016/j.ica.2019.119341

Publications 2019:

  1. «Highly Water-Soluble Amphiphilic Cyclodextrins bearing Branched and Cyclic Oleic Grafts»
    A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
    Eur. J. Org. Chem. 2019, 4863-4868
    - doi : 10.1002/ejoc.201900789

  2. «First evidence of cyclodextrin inclusion complexes in a deep eutectic solvent»
    T. Moufawad, L. Moura, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M. Costa Gomes, D. Landy, S. Fourmentin
    ACS SUSTAIN CHEM ENG, 2019, 7, 6, 6345–6351
    - doi: 10.1021/acssuschemeng.9b00044
    See «Publications marquantes 2019»

  3. «Synthesis of 2-Hydroxydodecyl Starch Ethers: Importance of the Purification Process»
    A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier, and S. Tilloy
    Ind. Eng. Chem. Res. 2019, 58, 7, 2437-2444
    - doi: 10.1021/acs.iecr.8b02605

  4. «Oleic Acid Based Cyclodextrins for the Development of New Hydrosoluble Amphiphilic Compounds»
    A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
    Eur. J. Org. Chem. 2019 , 1236–1241
    - doi: 10.1002/ejoc.201801609

Publications 2018:

  1. «Robust Mesoporous CoMo/γ-Al2O3 Catalysts from Cyclodextrin-Based Supramolecular Assemblies for Hydrothermal Processing of Microalgae: Effect of the Preparation Method»
    R. Bleta, B. Schiavo, N. Corsaro, P. Costa, A. Giaconia, L. Interrante, E. Monflier, G. Pipitone, A. Ponchel, S. Sau, O. Scialdone, S. Tilloy, A. Galia
    ACS Appl. Mater. Interfaces 2018, 10(15), 12562-12579
    - doi: 10.1021/acsami.7b16185
    See «Publications marquantes 2018»

  2. «New water-soluble Schiff base ligands based on β-cyclodextrin for aqueous biphasic hydroformylation reaction»
    M. Dauchy, M. Ferreira, J. Leblond, H. Bricout, S. Tilloy, G. S. Smith, E. Monflier
    Pure Appl. Chem., 2018, 90(5), 845-855
    -. doi: 10.1515/pac-2017-1205

  3. «Unconventional media and technologies for starch etherification and esterification»
    A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier and S. Tilloy
    Green Chem., 2018, 20, 1152–1168
    - doi: 10.1039/C7GC03135A
    See «Publications marquantes 2018»

Publications 2017:

  1. «Deep eutectic solvents: a promising medium for Volatile Organic Compounds absorption»
    L. Moura, T. Moufawad, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M.F. Costa Gomes, D. Landy, S. Fourmentin
    Environ. Chem. Lett. 2017, 15(4), 747-753
    - doi: 10.1007/s10311-017-0654-y

  2. «Water-soluble Phosphane-Substituted Cyclodextrin as Effective Bifunctional Additive in Hydroformylation of Higher Olefins»
    J. Leblond, J. Potier, S. Menuel, H. Bricout, C. Machut-Binkowski, D. Landy, S. Tilloy, E. Monflier, F. Hapiot
    Catal. Sci. Technol. 2017, 7, 3823 – 3830
    - doi: 10.1039/C7CY01108C
    See «Publications marquantes 2017»

  3. «Enhance the rheological and mechanical properties of clayey materials by adding starches»
    G. Alhaik, M. Ferreira, V. Dubois, E. Wirquin, S. Tilloy, E. Monflier, G. Aouad
    Constr. Build Mater., 2017, 139, 602-610
    - doi : 10.1016/j.conbuildmat.2016.11.130

  4. «Catalysis in cyclodextrin-based unconventional reaction media: recent developments and future opportunities»
    F. Hapiot, S. Menuel, M. Ferreira, B. Léger, H. Bricout, S. Tilloy, E. Monflier
    ACS Sustainable Chem. Eng. 2017, 5, 3598-3606
    - doi: 10.1021/acssuschemeng.6b02886
    See «Publications marquantes 2017»

  5. «Transition metal complexes coordinated by water soluble phosphane ligands: How cyclodextrins can alter the coordination Sphere?»
    M. Ferreira, H. Bricout, S. Tilloy, E. Monflier
    Molecules 2017, 22, 140
    - doi: 10.3390/molecules22010140

Publications 2016 :

  1. «Cyclodextrins as emerging therapeutic tools in the treatment of cholesterol-associated vascular and neurodegenerative diseases»
    C. Coisne, S. Tilloy, E. Monflier, D. Wils, L. Fenart, F. Gosselet
    Molecules, 2016, 21, 1748
    - doi: 10.3390/molecules21121748

  2. «Ring Opening Polymerization of ε-Caprolactone in the Presence of wet β-Cyclodextrin: Effect of the Operative Pressure and of Water Molecules in the β-Cyclodextrin Cavity»
    A. Galia, O. Scialdone, T. Spanò, M. Grazia Valenti, B. Grignard, P. Lecomte, E. Monflier, S. Tilloy and C. Rousseau
    RSC Adv., 2016, 6, 90290-90299
    - doi: 10.1039/C6RA20211J

  3. «Cleavage of Benzyl Phosphonium Salts as Efficient Bypass for Synthesis of Disulfonated Alkyldiphenylphosphanes Bearing an Oleum-Sensitive Alkyl Group»
    J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
    Eur. J. Org. Chem. 2016, 3322–3325
    - doi: 10.1002/ejoc.201600555

  4. «Methylated β-cyclodextrins decrease cholesterol release in smooth muscle cells and aortic endothelial cells via ABCA1- and ABCG1-mediated process»
    C. Coisne, D. Hallier-Vanuxeem, M-C. Boucau, J. Hachani, S. Tilloy, H. Bricout, E. Monflier, D. Wils, M. Serpelloni, X. Parissaux, L. Fenart, F. Gosselet
    Frontiers in Physiology, section Lipidology, 2016, 7, 185
    - doi: 10.3389/fphys.2016.00185

  5. «Cyclodextrins Modified by Metal-Coordinating Groups for Aqueous Organometallic Catalysis: What remains to be done?»
    S. Tilloy, H. Bricout, S. Menuel, F. Hapiot and E. Monflier
    Current Organocatalysis volume 3, pages 24-31, 2016

    doi: 10.2174/2213337202666150618192947

Publications 2015:

  1. «Tetrasulfonated 1,2-Bis(diphenylphosphanyl)ethane as a Building Block for the Synthesis of Disulfonated Alkyldiphenylphosphanes»
    J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
    Eur. J. Org. Chem 2015, 5509–5512
    - doi: 10.1002/ejoc.201500772

  2. «Recent developments in cyclodextrin-mediated aqueous biphasic hydroformylation and Tsuji-Trost reactions»
    F. Hapiot, S. Menuel, H. Bricout, S. Tilloy, E. Monflier
    Appl. Organometal. Chem. 2015, 29, 580–587
    - doi: 10.1002/aoc.3340

  3. «Ruthenium-containing β-cyclodextrin polymer globules for the catalytic hydrogenation of biomass-derived furanic compounds»
    R. Herbois, S. Noël, B. Léger, S. Tilloy, S. Menuel, A. Addad, B. Martel, A. Ponchel, E. Monflier
    Green Chem. 2015, 17, 2444 - 2454
    - doi: 10.1039/C5GC00005J
    See «Publications marquantes 2015»

  4. «Rhodium catalyzed hydroformylation assisted by cyclodextrins in biphasic medium: can sulfonated naphthylphosphanes lead to active, selective and recyclable catalytic species?»
    M. Elard, J. Denis, M. Ferreira, H. Bricout, D. Landy, S. Tilloy, E. Monflier
    Catalysis Today 247 (2015) 47–54
    - doi: 10.1016/j.cattod.2014.06.002

  5. «Rhodium Catalyzed Hydroformylation of 1-Decene in Low Melting Mixtures Based on Various Cyclodextrins and N,N’-Dimethylurea»
    M. Ferreira, F. Jérôme, H. Bricout, S. Menuel, D. Landy, S. Fourmentin, S. Tilloy, E. Monflier
    Catal. Com., 2015, 63, 62-65 -
    doi : 10.1016/j.catcom.2014.11.001

Publications 2014:

  1. «Synthesis and characterization of a new photoinduced switchable β-cyclodextrin dimer»
    F. Hamon, C. Blaszkiewicz, M. Buchotte, E. Banaszak-Léonard, H. Bricout, S. Tilloy, E. Monflier, C. Cézard, L. Bouteiller, C. Len and F. Djedaini-Pilard
    Beilstein J. Org. Chem. 2014, 10, 2874–2885
    - doi: 10.3762/bjoc.10.304

  2. «Low melting mixtures based on β-cyclodextrin derivatives and N,N’-dimethylurea as solvents for sustainable catalytic processes»
    F. Jerome, M. Ferreira, H. Bricout, S. Menuel, E. Monflier, S. Tilloy
    Green Chem., 2014, 16 (8), 3876 - 3880
    - doi: 10.1039/C4GC00591K
    See «Publications marquantes 2014»

  3. «Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis»
    F. Hapiot, H. Bricout, S. Menuel, S. Tilloy, E. Monflier
    Catal. Sci. Technol., 2014, 4, 1899-1908
    - doi: 10.1039/C4CY00005F





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