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Hervé Bricout was born in Maubeuge (France) in 1969. He received his Ph.D. degree from the University of Lille I in 1997 under the supervision of Professor A. Mortreux. During his Ph.D., he studied the catalytic properties of homogeneous nickel complexes in isomerization and substitution reactions of allylic compounds.
Then, he reached the L.P.C.I.A., in the research group directed by Professor Eric Monflier, and became «Maître de Conférences » in 1997.
His work in this group deals with biphasic catalysis mediated by metal complexes modified by watersoluble phosphanes, and assisted by cyclodextrins as polyvalent promoters : mass transfer and substrate selectivity enhancement agents but also host molecules able to generate specific catalytic species.


Publications 2023:

  1. «Exploiting poly(ε-caprolactone) grafted from hydrohydroxymethylated sunflower oil as biodegradable coating material of water-soluble fertilizers»
    A. El Mouat, T. El Assimi, M. Raihane, J. Ternel, H. Bricout, E. Monflier, S. Tilloy, M. Lahcini
    Progress in Organic Coatings 179 (2023) 107513
    - doi: 10.1016/j.porgcoat.2023.107513
    See «Publications marquantes 2023»

Publications 2022:

  1. «Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes»
    C. Becquet, M. Ferreira, H. Bricout, B. Quienne, S. Caillol, E. Monflier and S. Tilloy
    Green Chemistry, 2022, 24, 7906–7912
    - doi: 10.1039/D2GC02534E
    See «Publications marquantes 2022»

  2. «Promising Recyclable Ionic Liquid-Soluble Catalytic System for Reductive Hydroformylation»
    A. El Mouat, C. Becquet, J. Ternel, M. Ferreira, H. Bricout, E. Monflier, M. Lahcini, and S. Tilloy
    ACS Sustainable Chem. Eng, 10, 34, 11310–11319
    - doi : 10.1021/acssuschemeng.2c03302
    See «Publications marquantes 2022»

Publications 2021:

  1. «Reductive Hydroformylation of Isosorbide Diallyl Ether»
    J. Ternel, A. Lopes, M. Sauthier, C. Buffe, V. Wiatz, H. Bricout, S. Tilloy, and E. Monflier
    Molecules, 2021, 26, 7322 - doi: 10.3390/molecules26237322

  2. «Hydrohydroxymethylation of Ethyl Ricinoleate and Castor Oil»
    C. Becquet, F. Berche, H. Bricout, E. Monflier, S. Tilloy
    ACS Sustain Chem Eng, 2021, 9, 9444−9454 -
    doi: 10.1021/acssuschemeng.1c02924
    See also «Publications marquantes 2021»

  3. «Asymmetric hydrogenation of ethyl pyruvate over aqueous dispersed Pt nanoparticles stabilized by a cinchonidine-functionalized β-cyclodextrin»
    S. Noël, E. Caronia, H. Bricout, I. Chena Tichá, S. Menuel, A. Ponchel, S. Tilloy, A. Galia, E. Monflier, J. Jindřich, B. Léger
    Catal. Commun. 2021, 150, 106272
    - doi: 10.1016/j.catcom.2020.106272

  4.  «Epimerization of Isosorbide Catalyzed by Homogeneous Ruthenium-Phosphine Complexes: a New Step towards an Industrial Process»
    T. Vanbésien, T. Delaunay, V. Wiatz, S. Bigot, H. Bricout, S. Tilloy, E. Monflier
    Inorg. Chim. Acta 2021, 515, 120094
    - doi: 10.1016/j.ica.2020.120094

Publications 2020:

  1. «Catalytic reduction of 4-nitrophenol with gold nanoparticles stabilized by large-ring cyclodextrins»
    S. Noel, H. Bricout, A. Addad, C. Sonnendecker, W. Zimmermann, E. Monflier, B. Leger
    New J. Chem. 2020, 44, 21007-21011
    - doi: 10.1039/D0NJ03687K

  2. «Anionic Amphiphilic Cyclodextrins bearing Oleic Grafts for the Stabilization of Ruthenium Nanoparticles Efficient in Aqueous Catalytic Hydrogenation»
    A. Cocq, B. Léger; S. Noel; H. Bricout; F. Pilard; S. Tilloy; E. Monflier
    ChemCatChem 2020, 12, 1013-1018
    - doi: 10.1002/cctc.201901837

  3. «Multiscale Structure of Starches Grafted with Hydrophobic Groups: A new Analytical Strategy»
    C. Volant, A. Gilet, F. Beddiaf, M. Collinet-Fressancourt, X. Falourd, N. Descamps, V. Wiatz, H. Bricout, S. Tilloy, E. Monflier, C. Quettier, A. Mazzah, A. Rolland-Sabate
    Molecules 2020, 25, 2827
    - doi:10.3390/molecules25122827

  4. «New Lipidyl-Cyclodextrins Obtained by Ring Opening of Methyl Oleate Epoxide Using Ball Milling»
    E. Oliva, D. Mathiron, S. Rigaud, E. Monflier, E. Sevin, H. Bricout, S. Tilloy, F. Gosselet, L. Fenart, V. Bonnet, S. Pilard and F. Djedaini-Pilard
    Biomolecules, 2020, 10(2), 339
    - doi: 10.3390/biom10020339

  5. «Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins»
    A. Cocq, H. Bricout, F. Djedaïni-Pilard, S. Tilloy, E. Monflier
    Catalysts 2020, 10, 56
    - doi: 10.3390/catal10010056

Publications 2019:

  1. «Highly Water-Soluble Amphiphilic Cyclodextrins bearing Branched and Cyclic Oleic Grafts»
    A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
    Eur. J. Org. Chem. 2019, 4863-4868
    - doi : 10.1002/ejoc.201900789

  2. «First evidence of cyclodextrin inclusion complexes in a deep eutectic solvent»
    T. Moufawad, L. Moura, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M. Costa Gomes, D. Landy, S. Fourmentin
    ACS SUSTAIN CHEM ENG, 2019, 7, 6, 6345–6351
    - doi: 10.1021/acssuschemeng.9b00044
    See «Publications marquantes 2019»

  3. «Synthesis of 2-Hydroxydodecyl Starch Ethers: Importance of the Purification Process»
    A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier, and S. Tilloy
    Ind. Eng. Chem. Res. 2019, 58, 7, 2437-2444
    - doi: 10.1021/acs.iecr.8b02605

  4. «Oleic Acid Based Cyclodextrins for the Development of New Hydrosoluble Amphiphilic Compounds»
    A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
    Eur. J. Org. Chem. 2019 , 1236–1241
    - doi: 10.1002/ejoc.201801609

Publications 2018:

  1. «New water-soluble Schiff base ligands based on β-cyclodextrin for aqueous biphasic hydroformylation reaction»
    M. Dauchy, M. Ferreira, J. Leblond, H. Bricout, S. Tilloy, G. S. Smith, E. Monflier
    Pure Appl. Chem., 2018, 90(5), 845-855
    -. doi: 10.1515/pac-2017-1205

  2. «Unconventional media and technologies for starch etherification and esterification»
    A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier and S. Tilloy
    Green Chem., 2018, 20, 1152–1168
    - doi: 10.1039/C7GC03135A
    See «Publications marquantes 2018»

Publications 2017:

  1. «Deep eutectic solvents: a promising medium for Volatile Organic Compounds absorption»
    L. Moura, T. Moufawad, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M.F. Costa Gomes, D. Landy, S. Fourmentin
    Environ. Chem. Lett. 2017, 15(4), 747-753
    - doi: 10.1007/s10311-017-0654-y

  2. «Polyoxometalate, cationic cluster and g-cyclodextrin. From primary interactions to supramolecular hybrid materials»
    M. Aly Moussawi, N. Leclerc, P. Abramov, M.N. Sokolov, S. Cordier, A. Ponchel, E. Monflier, H. Bricout, D. Landy, M. Haouas, J. Marrot, E. Cadot
    J Am Chem Soc 2017, 139, 12793-12803
    - doi: 10.1021/jacs.7b07317
    See «Publications marquantes 2017»

  3. «Water-soluble Phosphane-Substituted Cyclodextrin as Effective Bifunctional Additive in Hydroformylation of Higher Olefins»
    J. Leblond, J. Potier, S. Menuel, H. Bricout, C. Machut-Binkowski, D. Landy, S. Tilloy, E. Monflier, F. Hapiot
    Catal. Sci. Technol. 2017, 7, 3823 – 3830
    - doi: 10.1039/C7CY01108C
    See «Publications marquantes 2017»

  4. «Green and scalable palladium on carbon-catalyzed Tsuji-Trost coupling reaction using an efficient and continuous flow system»
    C. Cazorla, M. Billamboz, H. Bricout, E. Monflier, C. Len
    Eur. J. Org. Chem., 2017, 1078-1085
    - doi: 10.1002/ejoc.201601311

  5. «Catalysis in cyclodextrin-based unconventional reaction media: recent developments and future opportunities»
    F. Hapiot, S. Menuel, M. Ferreira, B. Léger, H. Bricout, S. Tilloy, E. Monflier
    ACS Sustainable Chem. Eng. 2017, 5, 3598-3606
    - doi: 10.1021/acssuschemeng.6b02886
    See «Publications marquantes 2017»

  6. «Transition metal complexes coordinated by water soluble phosphane ligands: How cyclodextrins can alter the coordination Sphere?»
    M. Ferreira, H. Bricout, S. Tilloy, E. Monflier
    Molecules 2017, 22, 140
    - doi: 10.3390/molecules22010140

Publications 2016:

  1. «Cleavage of Benzyl Phosphonium Salts as Efficient Bypass for Synthesis of Disulfonated Alkyldiphenylphosphanes Bearing an Oleum-Sensitive Alkyl Group»
    J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
    Eur. J. Org. Chem. 2016, 3322–3325
    - doi: 10.1002/ejoc.201600555

  2. «Methylated β-cyclodextrins decrease cholesterol release in smooth muscle cells and aortic endothelial cells via ABCA1- and ABCG1-mediated process»
    C. Coisne, D. Hallier-Vanuxeem, M-C. Boucau, J. Hachani, S. Tilloy, H. Bricout, E. Monflier, D. Wils, M. Serpelloni, X. Parissaux, L. Fenart, F. Gosselet
    Frontiers in Physiology, section Lipidology, 2016, 7, 185
    - doi: 10.3389/fphys.2016.00185

  3. «Cyclodextrins Modified by Metal-Coordinating Groups for Aqueous Organometallic Catalysis: What remains to be done?»
    S. Tilloy, H. Bricout, S. Menuel, F. Hapiot and E. Monflier
    Current Organocatalysis volume 3, pages 24-31, 2016

    doi: 10.2174/2213337202666150618192947

Publications 2015:

  1. «Tetrasulfonated 1,2-Bis(diphenylphosphanyl)ethane as a Building Block for the Synthesis of Disulfonated Alkyldiphenylphosphanes»
    J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
    Eur. J. Org. Chem 2015, 5509–5512
    - doi: 10.1002/ejoc.201500772

  2. «Recent developments in cyclodextrin-mediated aqueous biphasic hydroformylation and Tsuji-Trost reactions»
    F. Hapiot, S. Menuel, H. Bricout, S. Tilloy, E. Monflier
    Appl. Organometal. Chem. 2015, 29, 580–587
    - doi: 10.1002/aoc.3340

  3. «Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands»
    K. Sordakis, A. Guerriero, H. Bricout, M. Peruzzini, P. J. Dyson, E. Monflier, F. Hapiot, L. Gonsalvi, G. Laurenczy
    Inorganica Chimica Acta 2015, 431, 132–138
    - doi: 10.1016/j.ica.2014.10.034

  4. «Rhodium catalyzed hydroformylation assisted by cyclodextrins in biphasic medium: can sulfonated naphthylphosphanes lead to active, selective and recyclable catalytic species?»
    M. Elard, J. Denis, M. Ferreira, H. Bricout, D. Landy, S. Tilloy, E. Monflier
    Catalysis Today 247 (2015) 47–54
    - doi: 10.1016/j.cattod.2014.06.002

  5. «Rhodium Catalyzed Hydroformylation of 1-Decene in Low Melting Mixtures Based on Various Cyclodextrins and N,N’-Dimethylurea»
    M. Ferreira, F. Jérôme, H. Bricout, S. Menuel, D. Landy, S. Fourmentin, S. Tilloy, E. Monflier
    Catal. Com., 2015, 63, 62-65 -
    doi : 10.1016/j.catcom.2014.11.001

Publications 2014:

  1. «Synthesis and characterization of a new photoinduced switchable β-cyclodextrin dimer»
    F. Hamon, C. Blaszkiewicz, M. Buchotte, E. Banaszak-Léonard, H. Bricout, S. Tilloy, E. Monflier, C. Cézard, L. Bouteiller, C. Len and F. Djedaini-Pilard
    Beilstein J. Org. Chem. 2014, 10, 2874–2885
    - doi: 10.3762/bjoc.10.304

  2. «Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-biaryl Sulfonated Phosphines in Aqueous Solution»
    A. Guerriero, H. Bricout, K. Sordakis, M. Peruzzini, E. Monflier, F. Hapiot, G. Laurenczy, L. Gonsalvi
    ACS Catalysis 2014, 4, 3002−3012
    - doi: 10.1021/cs500655x
    See «Publications marquantes 2014»

  3. «Low melting mixtures based on β-cyclodextrin derivatives and N,N’-dimethylurea as solvents for sustainable catalytic processes»
    F. Jerome, M. Ferreira, H. Bricout, S. Menuel, E. Monflier, S. Tilloy
    Green Chem., 2014, 16 (8), 3876 - 3880
    - doi: 10.1039/C4GC00591K
    See «Publications marquantes 2014»

  4. «Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis»
    F. Hapiot, H. Bricout, S. Menuel, S. Tilloy, E. Monflier
    Catal. Sci. Technol., 2014, 4, 1899-1908
    - doi: 10.1039/C4CY00005F

Selected publications :

  1. «Functionalized Cyclodextrins as First and Second Coordination Sphere Ligands for Aqueous Organometallic Catalysis»
    F. Hapiot, H. Bricout, S. Tilloy, E. Monflier
    Eur. J. Inorg. Chem. 2012, 1571–1578
    - doi: 10.1002/ejic.201101316

  2. «Cyclodextrin/Amphiphilic Phosphane Mixed Systems and their Applications in Aqueous Organometallic Catalysis»
    M. Ferreira, H. Bricout, N. Azaroual, D. Landy, S. Tilloy, Fr. Hapiot, E. Monflier
    Adv. Synth. Catal. 2012, 354, 1337-1346
    - doi: 10.1002/adsc.201100837
    See «Publications marquantes 2012»

  3. «Phosphane-based cyclodextrins as mass transfer agents and ligands for aqueous organometallic catalysis»
    S. Tilloy, C. Binkowski-Machut, S. Menuel, H. Bricout, E. Monflier
    Molecules 2012, 17, 13062-13072
    - doi: 10.3390/molecules171113062

  4. «Synthesis, Rhodium Complexes and Catalytic Applications of a New Water-Soluble Triphenylphosphane-Modified b-Cyclodextrin»
    F.X. Legrand, N. Six, C. Slomianny, H. Bricout, S. Tilloy, E. Monflier
    Adv. Synth. Catal. 2011, 353, 1325 – 1334
    - doi: 10.1002/adsc.201000917
    See «Publications marquantes 2011»

  5. «Properties and Catalytic Activities of New Easily-Made Amphiphilic Phosphanes for Aqueous Organometallic Catalysis»
    M. Ferreira, H. Bricout, N. Azaroual, C. Gaillard, D. Landy, S. Tilloy, E. Monflier
    Adv. Synth. Catal. 2010, 352, 1193-1203
    See «Publications marquantes 2010»

  6. «Amphiphilic photo-isomerizable phosphanes for aqueous organometallic catalysis»
    H. Bricout, E. Banaszak, C. Len, F. Hapiot, E. Monflier
    Chem. Commun. 2010, 46, 7813-7815
    - doi : 10.1039/C0CC02458A -
    See «Publications marquantes 2010»

  7. «Ditopic cyclodextrin-based receptors: New perspectives in aqueous organometallic catalysis»
    N. Six, S. Menuel, H. Bricout, F. Hapiot, E. Monflier
    Adv. Synth. Catal. 2010, 352, 1467-1475
    - doi : 10.1002/adsc.201000027 -
    See «Publications marquantes 2010»

  8. «Cyclodextrins as mass transfer additives in aqueous organometallic catalysis»
    H. Bricout, F. Hapiot, A. Ponchel, S. Tilloy, E. Monflier
    Curr Org Chem, 2010, 14 (13), 1296-1307





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